Stereochemical Studies. XXV. The Absolute Configuration and Optical Purity of (+)-4-Methyl-4-phenyl-2-cyclohexenone

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概要

• 論文の詳細を見る

• (+)-4-Methyl-4-phenyl-2-cyclohexenone ((+)-I), obtained by asymmetric synthesis, was chemically correlated to (S)-(+)-2-methyl-2-phenylbutanoic acid, whose absolute configuration is known. It was shown that (+)-4-methyl-4-phenyl-2-cyclohexenone ((+)-I) has (R) configuration. In determining the configuration, the optical ratation of optically pure (+)-4-methyl-4-phenyl-2-cyclohexenone ((+)-I) was estimated to be +130°in ethanol at D ray.

• 公益社団法人日本薬学会の論文
• 1973-10-25

著者

• 山田 俊一

  Faculty of Pharmaceutical Sciences, University of Tokyo

• 山田 俊一

  Faculty Of Pharmaceutical Sciences University Of Tokyo

• 大谷 元治

  Faculty of Pharmaceutical Sciences, University of Tokyo

• 大谷 元治

  Tokyo Research Laboratories Kowa Company Ltd.

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