Stereochemical Studies. XXXVI. Stereoselective Syntheses of trans- and cis-Cinnamic Acid Esters from the Phenylalanine Derivatives

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概要

• 論文の詳細を見る

• α-Diazo-β-phenyl-propionic acid esters (II) prepared from the phenylalanine derivatives (I) were readily decomposed by the alkoxide in tetrahydrofuran to give trans-cinnamic acid esters (III) stereoselectively, while the decomposition of II in the presence of boron trifluoride etherate and dicyclohexylcarbodiimide in methylene chloride afforded ciscinnamic acid esters (IV) as sole reaction products.

• 公益社団法人日本薬学会の論文
• 1975-02-25

著者

• 高村 則夫

  Organic Chemistry Research Laboratory, Tanabe Seiyaku Co., Ltd.,

• 山田 俊一

  Faculty of Pharmaceutical Sciences, University of Tokyo

• 山田 俊一

  Faculty Of Pharmaceutical Sciences University Of Tokyo

• 溝口 富茂

  Organic Chemistry Research Laboratory Tanabe Seiyaku Co. Ltd.

• 高村 則夫

  Organic Chemistry Research Laboratory Tanabe Seiyaku Co. Ltd.

• 溝口 富茂

  Organic Chemistry Research Laboratory, Tanabe Seiyaku Co., Ltd.

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