Mechanism of the Color Reaction of Active Methylene Compounds with 1,3,5-Trinitrobenzene Derivatives. I. Crystalline Products of the Color Reaction of Acetone with 1,3,5-Trinitrobenzene (Organic Analysis. LXXI)
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概要
- 論文の詳細を見る
Two coloring matters produced in the color reaction of acetone with excessive 1,3,5-trinitrobenzene in an alkaline medium were separated in crystalline forms and one of them was determined as the Meisenheimer type complex of acetone (I). The other was a new type complex (II) and was characterized as a sodium salt of the anion group shown in Chart 1. Spectrophotometric studies of I, II and the color reaction showed that I formed in the early stage of the reaction and then changed to II with time in the alkaline medium in the presence of excessive trinitrobenzene. In addition, a reason for increase of the color intensity in the improved procedures of the detection and determination of acetone was clarified by studying spectrophotometrically some behaviors of I and II.
- 公益社団法人日本薬学会の論文
- 1970-11-25
著者
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大倉 洋甫
Faculty Of Pharmaceutical Science Kyushu University
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小橋 一弥
Faculty Of Pharmaceutical Sciences Kyushu University
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百瀬 勉
Faculty Of Pharmaceutical Sciences Kyushu University
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百瀬 勉
Faculty Of Pharmaceutical Science Kyushu University
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