Mechanism of the Color Reaction of Active Methylene Compounds with 1,3,5-Trinitrobenzene Derivatives. V. A New Type and the Meisenheimer Type Coloring Matters of the Janovsky Reaction of Acetophenone and 1,3,5-Trinitrobenzene
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概要
- 論文の詳細を見る
Two main coloring matters were isolated in crystalline forms from an aqueous reaction mixture of acetophenone and 1,3,5-trinitrobenzene under the Janovsky conditions. One of them was the Meisenheimer type compound, sodium salt of II. The other was a new compound and the structure was determined as sodium salt of diphenacyltrinitrocyclohexenide anion III (Chart 3). The spectral behavior of these coloring matters was compared with that of the reaction mixture and the color reaction of acetophenone and TNB under the aqueous Janovsky conditions was discussed.
- 公益社団法人日本薬学会の論文
- 1973-10-25
著者
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百瀬 勉
Faculty of Pharmaceutical Science, Kyushu University
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大倉 洋甫
Faculty Of Pharmaceutical Science Kyushu University
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小橋 一弥
Faculty Of Pharmaceutical Sciences Kyushu University
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壁屋 豊繁
Faculty Of Pharmaceutical Sciences Kyushu University 62
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百瀬 勉
Faculty Of Pharmaceutical Sciences Kyushu University
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百瀬 勉
Faculty Of Pharmaceutical Science Kyushu University
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