O-Arenesulfonyl-N-alkylhydroxylamines as Aminating Reagents

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概要

• 論文の詳細を見る

• O-(p-Toluenesulfonyl)-N-methyl-, -N-ethyl-, and -N-isopropyl-hydroxylamines and O-mesitylenesulfonyl-N-methylhydroxylamine were prepared. The N-methyl and N-ethyl derivatives were found to react with tertiary amines and triphenylphosphine to give the corresponding N-(alkylamino) ammonium salts and P-(alkylamino) phosphonium salts, but the N-isopropyl derivative was less reactive, probably due to steric effects. These reagents also reacted with tri-n-butylborane to give the corresponding alkyl-n-butylamines.

• 公益社団法人日本薬学会の論文
• 1982-04-25

著者

• 田村 恭光

  Faculty Of Pharmaceutical Sciences Osaka University

• 池田 正澄

  Faculty of Pharmaceutical Sciences, Osaka University

• 池田 正澄

  Kyoto Pharmaceutical University

• 壺内 英継

  Microbiological Research Institute, Otsuka Pharmaceutical Co., Ltd.,

• 池田 裕之

  The Institute of Physical and Chemical Research

• 壺内 英継

  Faculty of Pharmaceutical Sciences, Osaka University

• 池田 裕之

  Faculty of Pharmaceutical Sciences, Osaka University

• 森田 岩男

  Faculty of Pharmaceutical Sciences, Osaka University

• 壺内 英継

  Microbiological Research Institute Otsuka Pharmaceutical Co. Ltd.

• 森田 岩男

  Research Laboratories Nippon Shinyaku Co. Ltd.

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