Adsorption Equilibria of Trimethylamine on Porous Adsorbents

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概要

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• Adsorption equilibria of trimethylamine as the offensive odor substance was measured by a gravimetric method to elucidate the mechanism of its adsorption on activated carbon, silicate, and zeolite. The mechanism of adsorption was discussed on the basis of application of the Dubinin-Astakhov equation to the adsorption isotherms and relation between the characteristic energy (E), exponent (n) and pore size distribution. The Dubinin-Astakhov equation was well applicable to the adsorption isotherms of activated carbon, silicate, and zeolite. The exponent (n) of activated carbon, silicate, and zeolite was 2,3,and 3,respectively. It was confirmed that the adsorption of trimethylamine on the adsorbents resulted in the volume filling of their micropores by the mechanism of capillary condensation, and that the two or three degrees of freedom in translation of trimethylamine was lost by its adsorption on the micropores or ultramicropores, respectively. The amount of trimethylamine adsorbed on the microporous adsorbents was determined by their micropore volume of pore radius less than about 20 Å.

• 公益社団法人日本薬学会の論文
• 1978-09-25

著者

• 田村 恭光

  Faculty Of Pharmaceutical Sciences Osaka University

• 松本 和興

  聖徳大学人文学部

• 坊木 佳人

  近畿大学薬学部

• 松本 和興

  Tokyo Food and Nutrition College

• 堀 義治

  Faculty of Pharmaceutical Science, Tokushima University of Arts and Science

• 当宮 辰美

  Anan Technical College

• 堀 義治

  徳島大医公衛

• 当宮 辰美

  徳島大医公衛

• 田村 恭光

  Faculty of Pharmaceutical Sciences, Osaka University

• 棚田 成紀

  Faculty of Pharmaceutical Sciences, Kinki University

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