Reaction of N-Haloamide. XI. Reaction of N, N-Dichlorobenzenesulfonamide and N, N-Dichlorobenzamide with Dihydropyran

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概要

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• The reaction of dihydropyran (I) with N, N-dichlorbenzenesulfonamide (II) and that with N, N-dichlorobenzamide (III) were studied. The reaction of I with II gave trans-2-benzenesulfonamido-3-chlorotetrahydropyran (V) and a minor product which is a cis-isomer of V. In the reaction of I with III, trans-2-benzamido-3-chlorotetrahydropyran (VIII), its cis-isomer (IX), 2-ethoxy-3-chlorotetrahydropyran (X), and benzamide (XI) were obtained. The reactions of N-haloamides, II, III, and N, N-dibromobenzenesulfonamide, with dihydropyran were compared and the mode of them were discussed.

• 公益社団法人日本薬学会の論文
• 1970-02-25

著者

• 竹村 庄司

  Faculty Of Pharmaceutical Sciences Kinki University

• 大槻 一夫

  Faculty Of Pharmaceutical Sciences Kinki University

• 上農 義雄

  Faculty of Pharmacy, Kinki University

• 竹村 庄司

  Faculty Of Pharmacy Kinki University

• 竹村 庄司

  近畿大薬

• 荻原(岡本) 捷子

  Faculty of Pharmacy, Kinki University

• 上農 義雄

  Faculty Of Pharmaceutical Sciences Kinki University

• 荻原(岡本) 捷子

  Faculty Of Pharmacy Kinki University

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