Reaction of N-Halosulfonamide. II. Reaction of N, N-Dihalobenzenesulfonamide with Cyclohexene. (2).

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概要

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• In order to examine the mode of reaction of N, N-dihalobenzenesulfonamide (I) with cyclohexene (II), the assumed intermediate, DL-trans-2,N-dibromo-1-benzenesulfonamidocy-clohexane (X), was synthesized and the formation of it in the pathway of the reaction of the bromo analog of I with II was proved. Comparing the behavior of N-bromo-N-methyl-benzenesulfonamide (XI) with that of X, the reaction of XI with II was examined, which afforded trans-1,2-dibromocyclohexane (V), 1,3-cyclohexadiene (VI), and 1-bromocyclohexene (XII). On the basis of these facts, the mechanism of the reaction of I with II was discussed.

• 公益社団法人日本薬学会の論文
• 1967-08-25

著者

• 竹村 庄司

  Faculty Of Pharmaceutical Sciences Kinki University

• 寺内 弘実

  近畿大学薬学部

• 安藤 佳子

  Faculty Of Pharmacy Kinki University

• 寺内 弘実

  Faculty of Pharmacy, Kinki University

• 上農 義雄

  Faculty of Pharmacy, Kinki University

• 竹村 庄司

  Faculty Of Pharmacy Kinki University

• 上農 義雄

  Faculty Of Pharmaceutical Sciences Kinki University

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