Reaction of N-Haloamide. XIII. The Coupled Reaction of N, N-Dibromobenzenesulfonamide and Formamide or Dimethylformamide with Cyclohexene

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概要

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• The reaction of N, N-dibromobenzenesulfonamide (I) with cyclohexene (II) in formamide or dimethylformamide were studied. The reaction of I with II in formamide gave a major product, trans-2-bromo-1-cyclohexyl N-benzenesulfonylformimidate (III), and minor products, trans-1,2-dibromocyclohexane (IV), trans-2-bromocyclohexyl formate (V), trans-2-bromocyclohexanol (VI) and benzenesulfonamide (VII). The reaction in dimethylformamide, contrary to that in formamide, gave another type of product, N, N-dimethyl-N'-benzenesulfonylformamidine (IX), IV, V and VI were also obtained as by-products. The mechanism to form these products was discussed.

• 公益社団法人日本薬学会の論文
• 1971-08-25

著者

• 竹村 庄司

  Faculty Of Pharmaceutical Sciences Kinki University

• 上農 義雄

  Faculty of Pharmacy, Kinki University

• 竹村 庄司

  Faculty Of Pharmacy Kinki University

• 竹村 庄司

  近畿大薬

• 新里 初美

  Faculty of Pharmaceutical Sciences, Kinki University

• 上農 義雄

  Faculty Of Pharmaceutical Sciences Kinki University

• 新里 初美

  Faculty Of Pharmaceutical Sciences Kinki University

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