Reaction of N-Haloamide. VIII. Reactions of N-Bromobenzenesulfonamides or Bromine with Benzylamines

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概要

• 論文の詳細を見る

• Reaction of N-bromo-N-benzylbenzenesulfonamide (2), N, N-dibromobenzenesulfonamide, and bromine with benzylamines were studied. Tertiary benzylamine degraded to secondary benzylamine hydrobromide and benzaldehyde, secondary benzylamine to primary benzylamine hydrobromide and benzaldehyde, and primary benzylamine to ammonia, benzaldehyde, and primary benzylamine hydrobromide in moist benzene. When the reaction was carried out in dried medium, several intermediates such as salts of benzalbenzylamine (8,9) and benzalbenzenesulfonamide were identified. The structure of an intermediate, benzalbenzylamine hydrobromide perbromide (9) was established.

• 公益社団法人日本薬学会の論文
• 1969-03-25

著者

• 竹村 庄司

  Faculty Of Pharmaceutical Sciences Kinki University

• 神谷 佳子

  Faculty Of Pharmaceutical Sciences Kinki University

• 寺内 弘実

  近畿大学薬学部

• 寺内 弘実

  Faculty of Pharmacy, Kinki University

• 上農 義雄

  Faculty of Pharmacy, Kinki University

• 竹村 庄司

  Faculty Of Pharmacy Kinki University

• 竹村 庄司

  近畿大薬

• 上農 義雄

  Faculty Of Pharmaceutical Sciences Kinki University

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