Reaction of N-Haloamide. XXV. Addition Reaction of N, N-Di-bromobenzenesulfonamide with Asymmetric Olefins and α, β-Unsaturated Carboxylic Acid Esters

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概要

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• In order to confirm the orientation of the addition of N, N-dibromobenzenesulfonamide (DBBS) to olefins, the reactions of DBBS with asymmetric alkenes and α, β-unsaturated carboxylic acid esters were examined. The additions of DBBS to alkenes proceeded by Markownikoff's fashion, and those to the unsaturated esters gave the products which have bromines at α-carbons and sulfonamido groups at β-positions. The reactions of DBBS with 1-methylcyclohexene, 2,3-dimethyl-1-butene, and 1,1-dimethyl-1-butene gave I, III, and IV, respectively. The reactions of DBBS with methyl methacrylate, methyl acrylate, and methyl crotonate gave V and VI, VIII and IX, and XI and XII, respectively.

• 公益社団法人日本薬学会の論文
• 1975-12-25

著者

• 竹村 庄司

  Faculty Of Pharmaceutical Sciences Kinki University

• 寺内 弘実

  近畿大学薬学部

• 寺内 弘実

  Faculty of Pharmacy, Kinki University

• 山崎 明美

  Faculty of Pharmaceutical Sciences, Kinki University

• 竹村 庄司

  Faculty Of Pharmacy Kinki University

• 竹村 庄司

  近畿大薬

• 山崎 明美

  Faculty Of Pharmaceutical Sciences Kinki University

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