Wagner-Meerwein Rearrangement of Allylbenzene Derivatives. I. Bromination of Safrole

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概要

• 論文の詳細を見る

• The reaction of safrole (I) with bromine (II) was examined giving different results from the literature, i.e., 2,3-dibromo-1-(3', 4'-methylenedioxyphenyl) propane (III), 1,3-dibromo-2-(3', 4'-methylenedioxyphenyl) propane (V) and their bromo-substituted derivatives (IV and VI) were obtained. The formation of rearranged adducts (V and VI) suggests that Wagner-Meerwein rearrangement occured during this addition. The relationship between the reaction conditions and the ratio of the products was investigated.

• 公益社団法人日本薬学会の論文
• 1975-03-25

著者

• 大槻 一夫

  Faculty Of Pharmaceutical Sciences Kinki University

• 入野 妙子

  Faculty of Pharmacy, Kinki University

• 入野 妙子

  Faculty Of Pharmaceutical Sciences Kinki University

関連論文

• Reaction of N-Haloamide. XIV. Reaction of N, N-Dichlorophenylacetamide with Cyclohexene
• Reaction of N-Haloamide. XI. Reaction of N, N-Dichlorobenzenesulfonamide and N, N-Dichlorobenzamide with Dihydropyran
• Reaction of N-Haloamide. X. Reaction of N, N-Dichlorobenzamide with Cyclohexene
• Reaction of Propenylbenzene Derivatives and Their Analogs. I. Reaction of N, N-Dibromobenzenesulfonamide with Propenylbenzene Derivatives
• Reaction of N-Haloamide. XXIII. Reaction of N, N-Dibromobenzenesulfonamide with Isosafrole
• Wagner-Meerwein Rearrangement of Allylbenzene Derivatives. I. Bromination of Safrole
• Reaction of N-Haloamide. XXII. Reaction of N, N-Dibromobenzenesulfonamide with Safrole
• Isomerization between trans-2-Benzenesulfonamido-3-bromotetrahydropyran and Its Isomer
• Reaction of N-Halosulfonamide. VI. Reaction of N-Bromobenzenesulfonamides with Dihydropyran. (2)
• Reaction of N-Halosulfonamide. V. Reaction of N, N-Dibromobenzenesulfonamide with Dihydropyran. (1)

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