Reaction of N-Haloamide. XXII. Reaction of N, N-Dibromobenzenesulfonamide with Safrole

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概要

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• N, N-Dibromobenzenesulfonamide (II) was made to react with safrole (I) to give 2-benzenesulfonamido-3-bromo-1-(3', 4'-methylenedioxyphenyl) propane (III), 2-benzenesulfonamido-3-bromo-1-(6'-bromo-3', 4'-methylenedioxyphenyl) propane (IV), 1-benzenesulfonamido-3-bromo-2-(3', 4'-methylenedioxyphenyl) propane (VI), 1-benzenesulfonamido-3-bromo-2-(6'-bromo-3', 4'-methylenedioxyphenyl) propane (VII) and a mixture of bromo-adducts of safrole (XI) as by-product. The productions of VI and VII show that a Wagner-Meerwein rearrangement occurred in the course of the addition of II to the double bond of I.

• 公益社団法人日本薬学会の論文
• 1975-03-25

著者

• 大槻 一夫

  Faculty Of Pharmaceutical Sciences Kinki University

• 入野 妙子

  Faculty of Pharmacy, Kinki University

• 入野 妙子

  Faculty Of Pharmaceutical Sciences Kinki University

関連論文

• Reaction of N-Haloamide. XIV. Reaction of N, N-Dichlorophenylacetamide with Cyclohexene
• Reaction of N-Haloamide. XI. Reaction of N, N-Dichlorobenzenesulfonamide and N, N-Dichlorobenzamide with Dihydropyran
• Reaction of N-Haloamide. X. Reaction of N, N-Dichlorobenzamide with Cyclohexene
• Reaction of Propenylbenzene Derivatives and Their Analogs. I. Reaction of N, N-Dibromobenzenesulfonamide with Propenylbenzene Derivatives
• Reaction of N-Haloamide. XXIII. Reaction of N, N-Dibromobenzenesulfonamide with Isosafrole
• Wagner-Meerwein Rearrangement of Allylbenzene Derivatives. I. Bromination of Safrole
• Reaction of N-Haloamide. XXII. Reaction of N, N-Dibromobenzenesulfonamide with Safrole
• Isomerization between trans-2-Benzenesulfonamido-3-bromotetrahydropyran and Its Isomer
• Reaction of N-Halosulfonamide. VI. Reaction of N-Bromobenzenesulfonamides with Dihydropyran. (2)
• Reaction of N-Halosulfonamide. V. Reaction of N, N-Dibromobenzenesulfonamide with Dihydropyran. (1)

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