Synthesis of a Potent Rhodomycin, Oxaunomycin, and Its Analogs

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概要

• 論文の詳細を見る

• Oxaunomycin (3) and its regioisomer (6) were synthesized by employing regioselective glycosidations of te C-7 hydroxyl group of 10-O-acetyl-β-rhodomycinone (16) and the C-10 hydroxyl group of the C-7,9-O phenylboronate (14), respectively, in the presence of trimethylsilyl trifluoromethanesulfonate. Under the Konigs-Knorr conditions, 16 was also glycosidated to provide a fluoro sugar analog (7).

• 1992-01-25

著者

• 田村 恭光

  Faculty Of Pharmaceutical Sciences Osaka University

• 桐原 正之

  Faculty Of Pharmaceutical Sciences Osaka University

• 北 泰行

  Faculty of Pharmaceutical Sciences, Osaka University

• 藤岡 弘道

  Faculty Of Pharmaceutical Sciences Osaka University

• 山本 博文

  Faculty of Pharmaceutical Sciences, Osaka University

• 前田 ひろし

  Faculty of Pharmaceutical Sciences, Osaka University

• 藤井 裕士

  Faculty of Pharmaceutical Sciences, Osaka University

• 山本 博文

  Faculty Of Pharmaceutical Sciences Osaka University

• 藤井 裕士

  Faculty Of Pharmaceutical Sciences Osaka University

• 前田 ひろし

  Faculty Of Pharmaceutical Sciences Osaka University

• 北 泰行

  Faculty Of Pharmaceutical Sciences Osaka University

• 田村 恭光

  Faculty of Pharmaceutical Sciences, Osaka University

• 中島 豊和

  Faculty of Pharmaceutical Sciences, Osaka University

• 藤岡 弘道

  Faculty of Pharmaceutical Sciences, Osaka University

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