An Artificial Plastic Receptor That Discriminates Axial Asymmetry
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概要
- 論文の詳細を見る
An artificial plastic receptor that can discriminate axial asymmetry of optically active binaphthyldiamine derivatives was prepared by the 'molecular imprinting' technique. A light-radical polymerization in the presence of an axially asymmetric compound, (R)-2, 2′-bis-methylcarbonylamino-1, 1′-binaphthyl(binaphthyldiamine bis-acetamide(BINADA-ac)) as a template molecule with methacrylic acid(MA) as a functional monomer, and ethyleneglycol dimethacrylate(EGDMA) as a crosslinker, at 4℃, The obtained polymer exhibited a superior enantioselectivity to the (R)-enantiomer by HPLC analyses. This plastic receptor should recognize the template molecule with its shape and character of its functional groups. It should be useful in the development of chiral stationary phases for the optical resolutions of axially asymmetric compounds.
- 社団法人日本生物工学会の論文
- 2000-12-25
著者
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FUKUSAKI EI-ICHIRO
Department of Biotechnology, Graduate School of Engineering, Osaka University
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KOBAYASHI AKIO
Department of Biotechnology, Graduate School of Engineering, Osaka University
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Fukusaki Ei-ichiro
Department Of Biotechnology Graduate School Of Engineering Osaka University
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Kajiyama Shin-ichiro
Department Of Biotechnology Graduate School Of Engineering Osaka University
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Kajiyama Shin-ichiro
Department Of Bioresources Chemistry Faculty Of Agriculture Okayama University:department Of Biotech
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SAIGO AKIRA
Department of Biotechnology, Graduate School of Engineering, Osaka University
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Saigo Akira
Department Of Biotechnology Graduate School Of Engineering Osaka University
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Kobayashi Akio
Department Of Biotechnology Graduate School Of Engineering Osaka University
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KOBAYASHI Akio
Department of Biochemistry, Shinshu University School of Medicine
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