Absolute Configuration of Dehydrodiconiferyl Alcohol
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概要
- 論文の詳細を見る
he absolute configuration of dehydrodiconiferyl alcohol was elucidated by chemical degradation. (+)-Dehydrodiconiferyl alcohol was prepared by optically resolving the recemate with HPLC and degraded to methylsuccinic acid. This methylsuccinic acid was the (R)-(+)-enantiomer, the optical purity of which was confirmed by HPLC after suitable conversion. This result shows that the absolute configuration of C-2 of (+)-dehydrodiconiferyl alcohol was S. H-2 and H-3 of (+)-dehydrodiconiferyl alcohol are trans, so the absolute configuration of C-3 must be R. Thus, (+)-dehydrodiconiferyl alcohol was 2S and 3R, and the (-)-enantiomer was 2R and 3S. The absolute configuration of natural glucosides of dehydrodiconiferyl alcohol was also elucidated.
- 社団法人日本農芸化学会の論文
- 1994-09-23
著者
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KOSHIMIZU Koichi
Department of Biotechnological Science, Faculty of Biology-Oriented Science and Technology, Kinki Un
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Koshimizu K
Department Of Food Science And Technology Faculty Of Agriculture Kyoto University
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Koshimizu Koichi
Faculty Of Agriculture Kyoto University
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Koshimizu K
Kinki Univ. Wakayama Jpn
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Hirai Nobuhiro
Department Of Food Science And Technology Faculty Of Agriculture Kyoto University
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Kato Masayoshi
Department of Ischemic Circulatory Physiology, University of Tokyo
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UDAGAWA Hiroaki
Department of Food Science and Technology, Faculty of Agriculture, Kyoto University
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Koshimizu Koichi
Department Of Biotechnological Science Faculty Of Biology-oriented Science And Technology Kinki Univ
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Okamoto Masahiko
Environmental Health Science Laboratory, Sumitomo Chemical Co. Ltd.
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Yamamuro Munehiro
Department of Food Science and Technology, Faculty of Agriculture, Kyoto University
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Hirai N
International Innovation Center Kyoto University
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Kato Masayoshi
Department Of Cardiovascular Medicine Graduate School Of Medicine University Of Tokyo
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Kato Masayoshi
Department Of Food Science And Technology Faculty Of Agriculture Kyoto University
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Koshimizu K
National Inst. Vegetables Ornamental Plants And Tea Shizuoka Jpn
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Okamoto Masahiko
Environmental Health Science Laboratory
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Udagawa Hiroaki
Department Of Food Science And Technology Faculty Of Agriculture Kyoto University
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Yamamuro Munehiro
Department Of Food Science And Technology Faculty Of Agriculture Kyoto University
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