A Tentative Phenomenological Theory of Incommensurate Phase Transitions in Biphenyl
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The UV and VUV spectra of Li-halide crystals doped with divalent transition metalions are studied. The observed bands are assigned to the charge-transfer (C.T.)transitions from the halogen p orbitals to the metal 31 orbitals irn the transition metalhexahalide complexes. The observed structures of C.T. bands are attributed to the levelsplitting of metal 3d orbitals of the C.T. states by the crystal-field and intra-ionicelectron-electron interactions, and the structures of the valence states consisting ofhalogen p orbitals.
- 社団法人日本物理学会の論文
- 1981-04-15
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