Study on the Ferroelectric Phase Transition in RbDSO_4 by NMR. : I. Deuteron Magnetic Resonance in Paraelectric Phase
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概要
- 論文の詳細を見る
The angular dependence of first order quadrupole shifts about three mutually perpendicular axes is measured at 20℃ and is analy sed by Volkoff method. Quadrupling constants at two symmetrically inequivalent sites are 171.5^+_-2.0 kHz in the hydrogen bond of 2.613 Å in length and 167.7^+_-2.0 kHz in the other one of 2.712 Å in length. The directions of the principal axes of electric field gradient are discussed in connection with theposition of deuterium in the hydrogen bond. It is concluded that the deuterium is not in a disordered stare, but in fact stays on acentric position in each hydrgen bond even in the paraelectric phase.
- 社団法人日本物理学会の論文
- 1974-07-15
著者
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Kasahara Masaru
Research Institute For Electronic Science Hokkaido University
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Tatsuzaki Itaru
Research Institute Of Applied Electricity Hokkaido University
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Kasahara Masaru
Reseach Institute For Electronic Science Hokkaido University
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