Behaviors of Absolute Densities of N, H, and NH3 at Remote Region of High-Density Radical Source Employing N2--H2 Mixture Plasmas
スポンサーリンク
概要
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For an innovation of molecular-beam-epitaxial (MBE) growth of gallium nitride (GaN), the measurements of absolute densities of N, H, and NH3 at the remote region of the radical source excited by plasmas have become absolutely imperative. By vacuum ultraviolet absorption spectroscopy (VUVAS) at a relatively low pressure of about 1 Pa, we obtained a N atom density of $9\times 10^{12}$ cm-3 for a pure nitrogen gas used, a H atom density of $7\times 10^{12}$ cm-3 for a gas composition of 80% hydrogen mixed with nitrogen gas were measured. The maximum density $2\times 10^{13}$ cm-3 of NH3 was measured by quadruple mass spectrometry (QMS) at $\text{H$_{2}$}/(\text{N$_{2}$}+\text{H$_{2}$})=60$%. Moreover, we found that N atom density was considerably affected by processing history, where the characteristic instability was observed during the pure nitrogen plasma discharge sequentially after the hydrogen-containing plasma discharge. These results indicate imply the importance of establishing radical-based processes to control precisely the absolute densities of N, H, and NH3 at the remote region of the radical source.
- 2011-01-25
著者
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KONDO Hiroki
Graduate School of Engineering, Nagoya University
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Hori Masaru
Graduate School Of Engineering Nagoya University
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KANO Hiroyuki
NU Eco-Engineering Co., Ltd.
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Den Shoji
Katagiri Engineering Co. Ltd.
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Takeda Keigo
Graduate School of Engineering, Nagoya University, Nagoya 464-8603, Japan
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Chen Shang
Graduate School of Engineering, Nagoya University, Nagoya 464-8603, Japan
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Ishikawa Kenji
Graduate School of Engineering, Nagoya University, Nagoya 464-8603, Japan
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Sekine Makoto
Graduate School of Engineering, Nagoya University, Nagoya 464-8603, Japan
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Kano Hiroyuki
NU Eco Engineering Co., Ltd., Miyoshi, Aichi 470-0201, Japan
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