Inter- and intramolecular rhodium-rhodium interactions in bis(bidentate isocyanide)rhodium(I) hexafluorophosphates.
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概要
- 論文の詳細を見る
The reaction of [RhCl(1,5-C<SUB>8</SUB>H<SUB>12</SUB>)]<SUB>2</SUB> with the stoichiometric amount of bidentate isocyanide followed by metathesis affords complexes of the types [Rh(L–L)<SUB>2</SUB>]PF<SUB>6</SUB> (L–L=CN(CH<SUB>2</SUB>)<SUB>8</SUB>NC (<B>1</B>), CN(CH<SUB>2</SUB>)<SUB>7</SUB>NC (<B>2</B>)) and [Rh<SUB>2</SUB>(L–L)<SUB>4</SUB>](PF<SUB>6</SUB>)<SUB>2</SUB> (L–L=CN(CH<SUB>2</SUB>)<SUB>6</SUB>NC (<B>3</B>), CN(CH<SUB>2</SUB>)<SUB>4</SUB>NC (<B>4</B>)). The electronic spectra at various concentrations reveal that in dilute solutions <B>1</B> and <B>2</B> exist as monomers with chelating isocyanides, while <B>3</B> and <B>4</B> form dimers with bridging isocyanides through intramolecular rhodium–rhodium interactions as the smallest unit. On the other hand, in concentrated solutions <B>1</B> and <B>2</B> form dimers and <B>4</B> tetramers through intermolecular Rh–Rh interactions.
- 公益社団法人 日本化学会の論文
著者
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Kawakami Katsuhiko
Department Of Anatomy Osaka City University Medical School
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Tanaka Toshio
Department Of Applied Physics Faculty Of Engineering Tokyo University
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Okajima Masaki
Department of Applied Chemistry, Faculty of Engineering, Osaka University
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