Efficient reduction of triphenylmethanol to triphenylmethane by 9,10-dihydro-10-methylacridine in the presence of perchloric acid.
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概要
- 論文の詳細を見る
Reduction of triphenylmethanol (Ph<SUB>3</SUB>COH) to triphenylmethane by an NADH model compound, 9,10-dihydro-10-methylacridine (AcrH<SUB>2</SUB>), proceeds very efficiently in the presence of perchloric acid (HClO<SUB>4</SUB>) in acetonitrile at 298 K via hydride transfer from AcrH<SUB>2</SUB> to triphenylmethyl cation (Ph<SUB>3</SUB>C<SUP>+</SUP>) which is formed by the dehydration of Ph<SUB>3</SUB>COH with HClO<SUB>4</SUB>. Mechanisms of hydride transfer reactions from NADH model compounds to Ph<SUB>3</SUB>C<SUP>+</SUP> are also discussed.
- 公益社団法人 日本化学会の論文
著者
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Fukuzumi Shunichi
Department Of Applied Chemistry Faculty Of Engineering Osaka University
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Ishikawa Masashi
Department Of Applied Chemistry And Chemical Engineering Faculty Of Engineering Yamaguchi University
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Tanaka Toshio
Department Of Applied Physics Faculty Of Engineering Tokyo University
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Goto Tatsushi
Department of Applied Chemistry, Faculty of Engineering, Osaka University
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Tanaka Toshio
Department of Applied Chemistry, Faculty of Engineering, Osaka Univeristy
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