Effects of Organic Additives on Lithium Insertion/extraction for Graphite Electrode in Ionic Liquid Electrolytes Based on Bis(fluorosulfonyl)imide
スポンサーリンク
概要
- 論文の詳細を見る
The electrochemical behavior of a graphitized electrode was investigated in a room-temperature ionic liquid based on bis(fluorosulfonyl)imide (FSI－) with the addition of propylene carbonate (PC) or vinylene carbonate (VC). The reversible, significant lithium-ion (Li+) insertion/extraction was observed in the additive-free FSI-based ionic liquid, while the additive systems showed weak, reversible responses (VC) and degraded responses (PC). AC impedance measurements suggested that the presence of FSI－ extremely reduces the electrode/electrolyte interface impedance, which allows Li+ to intercalate into a graphitized electrode reversibly. By contrast, the addition of VC inhibits the reversible Li+ intercalation in spite of FSI－ existence.
著者
-
Kikuta Manabu
Dai-ichi Kogyo Seiyaku Co. Ltd.
-
Ishikawa Masashi
Department Of Applied Chemistry And Chemical Engineering Faculty Of Engineering Yamaguchi University
-
SUGIMOTO Toshinori
Department of Chemistry and Materials Engineering, Faculty of Chemistry, Materials and Bioengineering, Kansai University
-
YAMAGATA Masaki
Department of Chemistry and Materials Engineering, Faculty of Chemistry, Materials and Bioengineering, Kansai University
-
KONO Michiyuki
Dai-ichi Kogyo Seiyaku Co., Ltd.
-
HANDA Norihisa
Department of Chemistry and Materials Engineering, Faculty of Chemistry, Materials and Bioengineering, Kansai University
-
ATSUMI Yosuke
Department of Chemistry and Materials Engineering, Faculty of Chemistry, Materials and Bioengineering, Kansai University
-
ISHIKO Eriko
Dai-ichi Kogyo Seiyaku Co., Ltd.
関連論文
- Aortico-pulmonary Paraganglioma : Case Report and Japanese Review
- Lymphoepithelial Cyst of the Pancreas that Was Difficult to Distinguish from Branch Duct-Type Intraductal Papillary Mucinous Neoplasm : Report of a Case
- Small Cell Lung Cancer Associated with Systemic Sclerosis
- Composite mucinous and granulosa cell tumor of the ovary
- Dacarbazine, Nimustine Hydrochloride, Cisplatin and Tamoxifen Combination Chemotherapy for Advanced Malignant Melanoma
- One-Electron and Two-Electron Redox Switch in the Reactions of 1,5-Dihydroflavin and Quinones Controlled by Acid and Base in Acetonitrile
- EP-P25 Enzymatic synthesis of peptides in ionic liquids(Section VII Enzyme and Protein Engineering)
- グラシ-カ-ボン上のナフィオン膜に固定されたセリウム(III)の電極触媒活性
- 非対称アンモニウム塩を含むゲル電解質を用いた電気二重層キャパシタの性能
- Double Mediatory System Involving a Flavin Analog and a p-Benzoquinone Derivative for Photoinduced Electrochemical Oxidation of Benzyl Alcohol to Benzaldehyde in Acetonitrile
- Electrocatalytic Befavior of Poly(2,5-dihydroxyaniline) Syntehsized by Electropolymerization in Aqueous Solutions
- Redox Behavior of Poly(2,5-dihydroxyaniline) Synthesized by Electropolymerization in Aqueous Solutions
- メソポア構造を有する活性炭繊維の電気二重層キャパシタへの適応
- LiMn2O4電極の放電容量に及ぼす電解液組成の影響
- リチウムイミド電解液中の添加剤によるリチウム負極界面の制御と充放電効率の改善
- 新規自然発症ミオシン6-nullマウスの表現型および発現解析
- In-Plane Second Harmonic Generations in Photonic Crystal Slabs of LiNbO3
- FSI系イオン液体中におけるLiNi/Mn/Co/O正極の充放電挙動
- Beneficial Effects of a Li Salt on Electrode Behavior in an Ionic Liquid for Electric Double Layer Capacitors
- 水系硝酸マグネシウム電解液のEDLCへの適用とその電気化学的挙動
- Application of Fluorine-containing Solvents to LiCoO2 Cathode in High Voltage Operation
- Effects of Organic Additives on Lithium Insertion/extraction for Graphite Electrode in Ionic Liquid Electrolytes Based on Bis(fluorosulfonyl)imide
- Efficient reduction of triphenylmethanol to triphenylmethane by 9,10-dihydro-10-methylacridine in the presence of perchloric acid.
- Excellent Frequency Response of Vertically Aligned MWCNT Electrode for EDLC