Semiconducting bis(dialkyldithiocarbamato)copper(III) cation-TCNQ radical anion and -bis(1,2-dicyano-1,2-ethylenedithiolato)nickel(III) anion salts: [Cu(S2CNR2)2]+TCNQ and [Cu(S2CNR2)2]+[Ni(S2C2(CN)2)2]- (R=Et, n-Pr, and n-Bu).
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概要
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The title salts were synthesized. Segregated columnar structures of the salts are suggested from their electronic spectra and electrical resistivities; 10<SUP>4</SUP>–10<SUP>5</SUP>Ω cm range at 25 °C with activation energies of 0.24–0.33 eV as compact samples.
- 公益社団法人 日本化学会の論文
著者
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Tanaka Toshio
Department of Applied Chemistry, Faculty of Engineering, Osaka Univeristy
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Yumoto Yoshiji
Department of Applied Chemistry, Faculty of Engineering, Osaka University
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