Syntheses and properties of oxomolybdenum(VI), -(V), and -(IV) complexes with ferrocenecarbodithioate.
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概要
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A series of ferrocenecarbodithioato–oxomolybdenum(VI), -(V), and -(IV) complexes, Mo<SUP>VI</SUP>O<SUB>2</SUB>(S<SUB>2</SUB>CC<SUB>5</SUB>H<SUB>4</SUB>Fe<SUP>II</SUP>C<SUB>5</SUB>H<SUB>5</SUB>)<SUB>2</SUB> (<B>1</B>), Mo<SUP>V</SUP><SUB>2</SUB>O<SUB>3</SUB>(S<SUB>2</SUB>CC<SUB>5</SUB>H<SUB>4</SUB>Fe<SUP>II</SUP>C<SUB>5</SUB>H<SUB>5</SUB>)<SUB>4</SUB> (<B>2</B>), and Mo<SUP>IV</SUP>O(S<SUB>2</SUB>CC<SUB>5</SUB>H<SUB>4</SUB>Fe<SUP>II</SUP>C<SUB>5</SUB>H<SUB>5</SUB>)<SUB>2</SUB> (<B>3</B>) have been prepared. Complex <B>2</B> under-goes a disproportionation reaction in solution and exists as an equilibrium mixture with <B>1</B> and <B>3</B>. Cyclic voltammograms of <B>1</B> and <B>3</B> display two and three sets of quasi-reversible couples, respectively, arising from stepwise redox reactions of the molybdenum and iron sites. Electronic spectra revealed that the oxidized species [Mo<SUP>VI</SUP>O<SUB>2</SUB>(S<SUB>2</SUB>CC<SUB>5</SUB>H<SUB>4</SUB>Fe<SUP>III</SUP>C<SUB>5</SUB>H<SUB>5</SUB>)<SUB>2</SUB>]<SUP>2<SUP>+</SUP></SUP>, [Mo<SUP>V</SUP>O(S<SUB>2</SUB>CC<SUB>5</SUB>H<SUB>4</SUB>Fe<SUP>II</SUP>C<SUB>5</SUB>H<SUB>5</SUB>)<SUB>2</SUB>]<SUP>+</SUP>, and [Mo<SUP>V</SUP>O(S<SUB>2</SUB>CC<SUB>5</SUB>H<SUB>4</SUB>Fe<SUP>III</SUP>C<SUB>5</SUB>H<SUB>5</SUB>)<SUB>2</SUB>]<SUP>3<SUP>+</SUP></SUP> generated electrochemically are considerably stable owing to the electron-donating ability of the ferrocenecarbodithioate ligand.
- 公益社団法人 日本化学会の論文
著者
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NAKAMOTO Masami
Osaka Municipal Technical Research Institute
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Tanaka Koji
Department Of 1st Internal Medicine Osaka Medical College
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Nakamoto Masami
Osaka Municipal Technical Research Institute, Morinomiya
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Tanaka Toshio
Department of Applied Chemistry, Faculty of Engineering, Osaka Univeristy
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Tanaka Koji
Department of Applied Chemistry, Faculty of Engineering, Osaka University
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