A rate study on the oxidative addition reactions of iodine toward tetrakis(2,4,6-trimethylphenyl and t-butyl isocyanide)rhodium(I) perchlorates.
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概要
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The reaction of [RhL<SUB>4</SUB>]ClO<SUB>4</SUB> (L=2,4,6-Me<SUB>3</SUB>C<SUB>6</SUB>H<SUB>2</SUB>NC and <I>t</I>-BuNC) with an equimolar amount of iodine yields a <I>trans</I> adduct, [RhI<SUB>2</SUB>L<SUB>4</SUB>]ClO<SUB>4</SUB>. The rate of this reaction in acetonitrile was measured employing a stopped-flow technique under pseudo-first-order conditions with excess iodine. The result indicates that the reaction proceeds <I>via</I> an intermediate which is presumably assigned to <I>cis</I>-[RhI<SUB>2</SUB>L<SUB>4</SUB>]ClO<SUB>4</SUB>, followed by intramolecular isomerization to the <I>trans</I> adduct.
- 公益社団法人 日本化学会の論文
著者
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Tanaka Toshio
Department of Applied Chemistry, Faculty of Engineering, Osaka Univeristy
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Kuwae Ryosho
Department of Applied Chemistry, Faculty of Engineering, Osaka University
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