Oxidation of N-Alkylhydroxylamines. II. Reaction of N-Alkylhydroxylamines with tert-Butylhydroperoxide
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概要
- 論文の詳細を見る
The title reaction in benzene gives a C-nitroso compound, tert-butanol and presumably water according to the equation : RNHOH+tert-BuOOH→R-N=O+tert-BuOH+H_2O During the reaction electron spin resonance (ESR) spectra due to [chemical formula]・is observed. In the presence of a large excess of N-alkylhydroxylamine, tert-butylhydroperoxide decomposes through a 1 : 2 complex with N-alkylhydroxylamine and the activation energy of the reaction is about 12 kcal. Unless N-alkylhydroxylamine is present in fairly large excess, tert-butylhydroperoxide decomposes by direct homolysis : tert-BuOOH→tert-BuO・+HO・ and the activation energy is about 33 kcal.
- 公益社団法人日本薬学会の論文
- 1972-05-25
著者
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枡井 雅一郎
Faculty Of Pharmaceutical Sciences Osaka University
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佐用 博照
Faculty of Pharmaceutical Sciences, Kobe-Gakuin University
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尾崎 茂子
Faculty Of Pharmaceutical Sciences Osaka University
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佐用 博照
Faculty Of Pharmaceutical Sciences Kobe-gakuin University
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