Reaction of Electrochemically Generated Triphenylphosphine Radical Cation with Amides and Ureas

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概要

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• Constant-current electrolysis of triphenylphosphine in dichloromethane in the presence of primary amides and N, N'-disubstituted ureas resulted in the formation of nitriles and carbodiimides, respectively. Dehydrosulfurization of thiobenzamide and N, N'-dicyclohexylthiourea was also effected by electrolysis under the same conditions, but probably through mechanisms different from those of dehydration of the corresponding amide and urea.

• 社団法人日本薬学会の論文
• 1985-01-25

著者

• 枡井 雅一郎

  Faculty Of Pharmaceutical Sciences Osaka University

• 大森 秀信

  Faculty of Pharmaceutical Sciences, Osaka University

• 大森 秀信

  Faculty Of Pharmaceutical Sciences Osaka University

• 水木 康之

  Faculty Of Pharmaceutical Sciences Osaka University

• 左海 清

  Faculty of Pharmaceutical Sciences, Osaka University

• 長井 紀子

  Faculty of Pharmaceutical Sciences, Osaka University

• 枡井 雅一郎

  大阪大学薬学部

• 長井 紀子

  Faculty Of Pharmaceutical Sciences Osaka University

• 左海 清

  Faculty Of Pharmaceutical Sciences Osaka University

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