Anodic Oxidation of Organophosphorus Compounds. III. Anodic Alkoxylation and Thioalkoxylation of Triphenylphosphine
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概要
- 論文の詳細を見る
Controlled potential electrolysis of triphenylphosphine in acetonitrile containing various primary alcohols and dialkyldisulfides resulted in the formation of the corresponding alkoxy and alkylthio triphenylphosphonium salts, [Ph_3P^+-X] [ClO_4^-]. Compounds with X=OMe, OEt, OPr^n, SMe, SEt, and SPr^n were isolated. The alkoxy derivatives reacted with imidazole and thiophenol under mild conditions to give the corresponding N- and S-alkylated products quantitatively.
- 社団法人日本薬学会の論文
- 1980-03-25
著者
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枡井 雅一郎
Faculty Of Pharmaceutical Sciences Osaka University
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関口 昌宏
Faculty Of Pharmaceutical Sciences Osaka University
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大森 秀信
Faculty of Pharmaceutical Sciences, Osaka University
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中井 史郎
Faculty of Pharmaceutical Sciences, Osaka University
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桝井 雅一郎
Faculty of Pharmaceutical Sciences, Osaka University
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中井 史郎
Faculty Of Pharmaceutical Sciences Osaka University
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桝井 雅一郎
Faculty Of Pharmaceutical Sciences Osaka University
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大森 秀信
Faculty Of Pharmaceutical Sciences Osaka University
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桝井 雅一郎
Pharmaceutical Institute Medical Faculty University Of Tokyo
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