Preparation of Alkyl Thiocyanates by Electrochemical Oxidation of Thiocyanate Ion in the Presence of Alcohols and Triphenylphosphite
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概要
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Conversion of primary alcohols to the corresponding thiocyanates was effected by constant-current electrolysis of thiocyanate ion in dichloromethane containing an alcohol, triphenylphosphite, and 2,6-lutidinium perchlorate or tetrafluoroborate. The electrolysis was performed at ambient temperature in a one-compartment cell using a graphite plate and a platinum plate as the anode and the cathode, respectively. 2,6-Lutidinium cation effectively extracted thiocyanate ion into the organic phase from sodium thiocyanate suspended in the reaction mixture.
- 公益社団法人日本薬学会の論文
- 1990-05-25
著者
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川口 知子
Faculty Of Pharmaceutical Sciences Osaka University
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枡井 雅一郎
Faculty Of Pharmaceutical Sciences Osaka University
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大森 秀信
Faculty of Pharmaceutical Sciences, Osaka University
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大森 秀信
Faculty Of Pharmaceutical Sciences Osaka University
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前田 初男
阪大薬
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前田 初男
大阪大学薬学部
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前田 初男
Faculty of Pharmaceutical Sciences, Osaka University
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前田 初男
Faculty Of Pharmaceutical Sciences Osaka University
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枡井 雅一郎
大阪大学薬学部
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