Electrochemical Transformation of N-Nitrosodialkylamines into N-Nitramines and β-Ketonitrosamines
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概要
- 論文の詳細を見る
Controlled potential electrolysis, based on the results of cyclic voltammetry, of simple dialkylnitrosamines such as N-nitrosodibutylamine and N-nitrosodicyclohexylamine in acetonitrile at a glassy carbon electrode resulted in the formation of the corresponding nitramines as the major products together with β-ketonitrosamines in which the carbonyl group is on the same side of the nitroso-oxygen atom. With N-nitrosopiperidine, one derived from a cyclic amine, N-nitropiperidine was formed similarly but the β-oxidized nitrosamine was not detected in the electrolysis solution. In deoxygenated acetonitrile, neither the nitramines nor the β-ketonitrosamines were obtained from the electrolysis.
- 社団法人日本薬学会の論文
- 1981-12-25
著者
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野瀬 浩一
Tsukuda Research Laboratories Eisai Co. Ltd.
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枡井 雅一郎
Faculty Of Pharmaceutical Sciences Osaka University
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大森 秀信
Faculty of Pharmaceutical Sciences, Osaka University
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田中 愛子
Faculty Of Pharmaceutical Sciences Osaka University
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大森 秀信
Faculty Of Pharmaceutical Sciences Osaka University
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野瀬 浩一
Faculty of Pharmaceutical Sciences, Osaka University
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山川 栄子
Faculty of Pharmaceutical Sciences, Osaka University
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枡井 雅一郎
大阪大学薬学部
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山川 栄子
Faculty Of Pharmaceutical Sciences Osaka University
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