Anodic Pyridination of 2,6-Di-tert-butyl-4-methylphenol

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概要

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• Anodic pyridination of 2,6-di-tert-butyl-4-methylphenol (1) in acetonitrile gave the corresponding 4-pyridinated cyclohexadienone and the side-chain pyridinated phenol. The yield of the former dienone decreased and that of the latter product increased with increase in the amount of added bases, pyridine and/or 2,6-lutidine. On the other hand, the product distribution in the methoxylation of 1 in methanol or in acetonitrile containing methanol was little affected by the addition of 2,6-lutidine, and 4-methoxylated dienone was the main product.

• 公益社団法人日本薬学会の論文
• 1982-10-25

著者

• 枡井 雅一郎

  Faculty Of Pharmaceutical Sciences Osaka University

• 大森 秀信

  Faculty of Pharmaceutical Sciences, Osaka University

• 大森 秀信

  Faculty Of Pharmaceutical Sciences Osaka University

• 植田 千裕

  Faculty of Pharmaceutical Sciences, Osaka University

• 植田 千裕

  大阪大学薬学部

• 徳野 美

  Faculty of Pharmaceutical Sciences, Osaka University

• 徳野 美

  Faculty Of Pharmaceutical Sciences Osaka University

• 枡井 雅一郎

  大阪大学薬学部

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