Saponin and Sapogenol. XXIX. Selective Cleavage of the Glucuronide Linkage in Oligoglycosides by Anodic Oxidation
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概要
- 論文の詳細を見る
In the course of studies aimed at finding a new selective cleavage method for the glucuronide linkage in glucuronide-saponins, an electrolytic oxidation reaction has been found to be useful as an initial reaction for the desired selective cleavage method. The new cleavage method comprises an anodic oxidation of glucuronide-saponin, by which the carboxyl function is converted to an acetoxyl moiety, and a subsequent alkali treatment. It has also been found that the anodic oxidation causes selective oxidation of axial hydroxyl groups and allylic oxidation in the sapogenol moiety.
- 公益社団法人日本薬学会の論文
- 1980-10-25
著者
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大森 秀信
Faculty of Pharmaceutical Sciences, Osaka University
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大森 秀信
Faculty Of Pharmaceutical Sciences Osaka University
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吉川 雅之
Faculty of Pharmaceutical Sciences, Osaka University
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北川 勲
Faculty Of Pharmaceutical Sciences Osaka University
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上垣内 俊行
Faculty of Pharmaceutical Sciences, Osaka University
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上垣内 俊行
Faculty Of Pharmaceutical Sciences Osaka University
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