Saponin and Sapogenol. XXXIII. Chemical Constituents of the Seeds of Vigna angularis (WILLD.) OHWI et OHASHI. (3). Azukisaponins V and VI

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概要

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• The chemical structures of azukisaponins V (1) and VI (5), two of the six oligoglycosidic ingredients of total azukisaponin isolated from azuki beans, the seeds of Vigna angularis (WILLD.) OHWI et OHASHI (Leguminosae), were investigated. By means of photochemical degradation and chemical analyses, the structures of azukisaponins V and VI were elucidated to be 3-O-[α-L-rhamnopyranosyl (1→2)-β-D-glucopyranosyl (1→2)-β-D-glucuronopyranosyl]-soyasapogenol B (1) and 3-O-[β-D-glucopyranosyl (1→2)-β-D-glucuronopyranosyl]-29-O-[β-D-glucopyranosyl (1→6)-β-D-glucuronopyranosyl] azukisapogenol (5), respectively. Azukisaponin VI (5) is the first reported example of a 3,29-bisdesmoside of an oleanene oligoglycoside.

• 公益社団法人日本薬学会の論文
• 1983-02-25

著者

• 北川 勲

  Faculty of Pharmaceutical Sciences, Osaka University

• 斎藤 雅之

  大阪大学 薬

• 吉川 雅之

  Faculty of Pharmaceutical Sciences, Osaka University

• 北川 勲

  Faculty Of Pharmaceutical Sciences Osaka University

• 王 惠康

  Faculty of Pharmaceutical Sciences, Osaka University

• 斎藤 雅之

  Faculty of Pharmaceutical Sciences, Osaka University

• 斎藤 雅之

  Faculty Of Pharmaceutical Sciences Osaka University

• 王 惠康

  Faculty Of Pharmaceutical Sciences Osaka University

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