Saponin and Sapogenol. L. On the Constituents of the Roots of Glycyrrhiza uralensis FISCHER from Xinjiang, China. Chemical Structures of Licorice-Saponin L3 and Isoliquiritin Apioside

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概要

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• From the air-dried roots of Glycyrrhiza uralensis FISCHER collected in Xinjiang province, China ("Shinkyo-Kanzo" in Japanese), a new oleanene-type triterpene oligoglycoside named licorice-saponin L3 and a new chalcone oligoglycoside named isoliquiritin apioside were isolated together with glycyrrhizin, 18α-glycyrrhizin, apioglycyrrhizin, arabo-glycyrrhizin, licorice-saponins A3,E2,G2,and H2,and six known flavonoid glycosides. On the basis of chemical and physicochemical evidence, the structures of licorice-saponin L3 and isoliquiritin apioside were elucidated as 3β-[α-L-rhamnopyranosyl(1→2)-α-L-arabinopyranosyl(1→2)-β-D-glucuronopyranosyloxy]-22β-acetoxy-24-hydroxyolean-12-en-30-oic acid (1) and 4-O-[β-D-apiofuranosyl(1→2)-β-D-glucopyranosyl]isoliquiritigenin (6), respectively.

• 公益社団法人日本薬学会の論文
• 1993-09-15

著者

• 内田 英美子

  大阪大学 薬

• 北川 勲

  Faculty of Pharmaceutical Sciences, Osaka University

• 堀 一之

  大阪大学薬学部

• 堀 一之

  Faculty of Pharmaceutical Sciences, Osaka University

• 内田 英美子

  Faculty Of Pharmaceutical Sciences Osaka University

• 陳 偉衆

  Faculty of Pharmaceutical Sciences, Osaka University

• 吉川 雅之

  Faculty of Pharmaceutical Sciences, Osaka University

• 任 家礼

  Xinjiang Institute of Chemistry, Academia Sinica

• 北川 勲

  Faculty Of Pharmaceutical Sciences Osaka University

• 陳 偉衆

  大阪大学薬学部

• 任 家礼

  中国科学院新疆化学研究所

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