Chemical Transformation of Terpenoids. I. Syntheses of (3S)-1-Vinyl-, (3S)-1-Hydroxypropenyl-, and (3S)-1-Epoxyethyl-1,2,2-trimethylcyclopentane Derivatives from d-Camphor via d-Camphoric Acid
スポンサーリンク
概要
- 論文の詳細を見る
As part of a series of studies on the transformation of terpenoids, four 1,2,2-trimethyl-cyclopentane derivatives, i.e., (+)-(1S, 3S)-3-acetoxymethyl-1,2,2-trimethyl-1-vinylcyclopentane (5), (+)-(1S, 3S)-3-acetoxymethyl-1-(3'-hydroxypropenyl)-1,2,2-trimethylcyclopentane (7), (+)-(1R, 3S, 1'S)-3-acetoxymethyl-1-(1', 2'-epoxyethyl)-1,2,2-trimethylcyclopentane (8), and (+)-(1R, 3S, 1'R)-3-acetoxymethyl-1-(1', 2'-epoxyethyl)-1,2,2-trimethylcyclopentane (9), were synthesized from d-camphor (1) via d-camphoric acid (2). All four compounds (5,7,8,9) retain the C-4 configuration of d-camphor at their C-3 positions.
- 社団法人日本薬学会の論文
- 1981-09-25
著者
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北川 勲
Faculty of Pharmaceutical Sciences, Osaka University
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山本 佳男
Faculty Of Pharmaceutical Sciences Osaka University
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渋谷 博孝
Faculty of Pharmaceutical Sciences, Osaka University
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藤岡 弘道
Faculty Of Pharmaceutical Sciences Osaka University
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辻井 伸治
Faculty of Pharmaceutical Sciences, Osaka University
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梶原 彰治
Faculty of Pharmaceutical Sciences, Osaka University
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高木 昭
Faculty of Pharmaceutical Sciences, Osaka University
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堀 学
Faculty of Pharmaceutical Sciences, Osaka University
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北川 勲
Faculty Of Pharmaceutical Sciences Osaka University
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堀 学
New Drug Research Laboratories, Kanebo Ltd.,
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堀 学
New Drug Research Laboratories Kanebo Ltd.
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辻井 伸治
Faculty Of Pharmaceutical Sciences Osaka University
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梶原 彰治
Faculty Of Pharmaceutical Sciences Osaka University
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