Saponin and Sapogenol. XLVIII. On the Constituents of the Roots of Glycyrrhiza uralensis FISCHER from Northeastern China. (2).Licorice-saponins D3,E2,F3,G2,H2,J2,and K2

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概要

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• Following the characterization of licorice-saponins A3 (2), B2 (3), and C2 (4), the chemical structures of licorice-saponins D3 (5), E2 (6), F3 (7), G2 (8), H2 (9), J2 (10), and K2 (11), seven of the ten oleanane-type triterpene oligoglycosides isolated from the air-dried roots of Glycyrrhiza uralensis FISCHER collected in the northeastern part of China, were investigated. On the basis of chemical and physicochemical evidence, the structures of licorice-saponins D3,E2,F3,G2,H2,J2,and K2 have been determined to be expressed as 3β-[α-L-rhamnopyranosyl(1→2)-β-D-glucuronopyranosyl(1→2)-β-D-glucuronopyranosyloxy]-22β-acetoxyolean-12-en-30-oic acid (5), 3-O-[β-D-glucuronopyranosyl(1→2)-β-D-glucuronopyranosyl]glabrolide (6), 3-O-[α-L-rhamnopyranosyl(1→2)-β-D-glucuronopyranosyl-(1→2)-β-D-glucuronopyranosyl]-11-deoxoglabrolide (7), 24-hydroxyglycyrrhizin (8), 3-O-[β-D-glucuronopyranosyl-(1→2)-β-D-glucuronopyranosyl]liquiritic acid (9), 24-hydroxy-11-deoxoglycyrrhizin (10), and 3β-[β-D-glucuronopyranosyl(1→2)-β-D-glucuronopyranosyloxy]-24-hydroxyoleana-11,13(18)-dien-30-oic acid (11), respectively.

• 公益社団法人日本薬学会の論文
• 1993-08-15

著者

• 北川 勲

  Faculty of Pharmaceutical Sciences, Osaka University

• 周 軍良

  Faculty Of Pharmaceutical Sciences Osaka University

• 堀 一之

  大阪大学薬学部

• 堀 一之

  Faculty of Pharmaceutical Sciences, Osaka University

• 吉川 雅之

  Faculty of Pharmaceutical Sciences, Osaka University

• 阪上 昌浩

  Research Foundation Itsuu Laboratory

• 北川 勲

  Faculty Of Pharmaceutical Sciences Osaka University

• 阪上 昌浩

  Faculty of Pharmaceutical Sciences, Osaka University

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