Saponin and Sapogenol. XLVII.On the Constituents of the Roots of Glycyrrhiza uralensis FISCHER from Northeastern China. (1). Licorice-Saponins A3,B2,and C2

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概要

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• From the air-dried root of Glycyrrhiza uralensis, collected in the northeastern part of China, ten new oleanane-type triterpene oligoglycosides were isolated together with glycyrrhizin (1) and several known flavonoids. Among the newly isolated triterpene oligoglycosides, the chemical structures of licorice-saponin A3 (2), licorice-saponin B2 (3), and licorice-saponin C2 (4) have been determined, on the basis of chemical and physicochemical evidence, to be expressed as 30-O-β-D-glucopyranosylglycyrrhizm, 11-deoxo-glycyrrhizin, and 3-O-[β-D-glucuronopyranosyl(1→2)-β-D-glucuronopyranosyl]oleana-11,13(18)-dien-30-oic acid, respectively. During the course of these studies, facile conversions from glycyrrhizn (1) to licorice-saponins A3 (2), B2 (3), and C2 (4) have been accomplished.

• 公益社団法人日本薬学会の論文
• 1993-01-15

著者

• 北川 勲

  Faculty of Pharmaceutical Sciences, Osaka University

• 周 軍良

  Faculty Of Pharmaceutical Sciences Osaka University

• 堀 一之

  大阪大学薬学部

• 堀 一之

  Faculty of Pharmaceutical Sciences, Osaka University

• 谷山 登志男

  小城製薬研究所

• 谷山 登志男

  Kyoto Pharmaceutical Univ. Kyoto Jpn

• 吉川 雅之

  Faculty of Pharmaceutical Sciences, Osaka University

• 北川 勲

  Faculty Of Pharmaceutical Sciences Osaka University

• 谷山 登志男

  Faculty of Pharmaceutical Sciences, Osaka University

• Taniyama T

  Kyoto Pharmaceutical Univ. Kyoto Jpn

• 谷山 登志男

  Faculty Of Pharmaceutical Sciences Osaka University

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