Electrochemical Oxidation of 2,6-Di-tert-butyl-4-methylphenol in Basic Methanol
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概要
- 論文の詳細を見る
Electrochemical oxidation of 2,6-di-tert-butyl-4-methylphenol (1) in methanol containing sodium methoxide gave side-chain-oxidized phenols, ArCH_2OMe, ArCHO, and ArCOOMe (Ar=3,5-di-tert-butyl-4-hydroxyphenyl), together with 2,6-di-tert-butylbenzoquinone and 3,5,3', 5'-tetra-tert-butyl-4,4'-diphenoquinone. The product distribution varied with the electricity consumption. Based on the results obtained, a simple electrochemical transformation of 1 to the hydroxybenzaldehyde ArCHO was effected.
- 公益社団法人日本薬学会の論文
- 1985-09-25
著者
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枡井 雅一郎
Faculty Of Pharmaceutical Sciences Osaka University
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大森 秀信
Faculty of Pharmaceutical Sciences, Osaka University
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大森 秀信
Faculty Of Pharmaceutical Sciences Osaka University
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前田 初男
阪大薬
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前田 初男
大阪大学薬学部
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前田 初男
Faculty of Pharmaceutical Sciences, Osaka University
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前田 初男
Faculty Of Pharmaceutical Sciences Osaka University
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植田 千裕
Faculty of Pharmaceutical Sciences, Osaka University
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植田 千裕
大阪大学薬学部
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徳野 美
Faculty of Pharmaceutical Sciences, Osaka University
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徳野 美
Faculty Of Pharmaceutical Sciences Osaka University
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枡井 雅一郎
大阪大学薬学部
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