Voltammetric Behavior of Triphenylphosphine in Acetonitrile at a Glassy Carbon Electrode : A Reinvestigation
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概要
- 論文の詳細を見る
Cyclic voltammetry of Ph_3P (1) in MeCN at a glassy carbon electrode showed two closely located anodic peaks. The first anodic peak corresponds to the oxidation of 1 to give Ph_3P=O and Ph_3PH^+ (2), where water contaminating the medium is the source of the oxygen and the porton. The second peak, which was depressed by an increase in voltage sweep rate, is suggested to involve the oxidation of 1 preceded by a slow deprotonation of 2 formed at the first anodic peak.
- 公益社団法人日本薬学会の論文
- 1988-05-25
著者
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枡井 雅一郎
Faculty Of Pharmaceutical Sciences Osaka University
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大森 秀信
Faculty of Pharmaceutical Sciences, Osaka University
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大森 秀信
Faculty Of Pharmaceutical Sciences Osaka University
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前田 初男
阪大薬
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前田 初男
大阪大学薬学部
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前田 初男
Faculty of Pharmaceutical Sciences, Osaka University
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前田 初男
Faculty Of Pharmaceutical Sciences Osaka University
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植田 千裕
Faculty of Pharmaceutical Sciences, Osaka University
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植田 千裕
大阪大学薬学部
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枡井 雅一郎
大阪大学薬学部
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