Oxidation of N-Alkylhydroxylamines. V. Anodic Oxidation of N, O-Dialkyl- and N, N, O-Trialkylhydroxylamines
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概要
- 論文の詳細を見る
The anodic oxidation of N, O-dialkyl- and N, N, O-trialkylhydroxylamines in acetonitrile was studied. These hydroxylamines generally showed two waves at a glassy-carbon electrode and the Ep values were larger than those of N-alkyl- and N, N-dialkylhydroxylamines. N, O-Diethyl and N-ethyl-O-t-butylhydroxylamine gave O-ethylacetaldoxime and O-t-butylacetaldoxime, respectively, as the major oxidation product, which suggests that N-alkoxy-N-alkylamino radical was a transient intermediate in the anodic oxidation.
- 公益社団法人日本薬学会の論文
- 1975-08-25
著者
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枡井 雅一郎
Faculty Of Pharmaceutical Sciences Osaka University
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佐用 博照
Faculty of Pharmaceutical Sciences, Kobe-Gakuin University
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佐用 博照
Faculty Of Pharmaceutical Sciences Kobe-gakuin University
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