Studies on Sulfenamides. IX. Anodic Oxidation of N-(o-Nitrophenylthio) alicyclic Amines
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概要
- 論文の詳細を見る
Cation radicals generated by anodic oxidation of N-(o-nitrophenylthio) alicyclic amines (morpholine (1), thiomorpholine (tetrahydro-4H-1,4-thiazine) (2), piperidine (3), pyrrolidine (4)) in acetonitrile were studied by cyclic voltammetry (CV) and electron spin resonance spectroscopy (ESR). 2-(o-Nitrophenylthio) indan-l-ol (6) was obtained from the solution after controlled potential electrolysis (CPE) of 1-3 in acetonitrile containing indene (5) and 0.1 M NaClO_4 at a glassy carbon anode. The cation radicals produced by CPE of 1-3 attacked 5 to give 6 as a final product.
- 公益社団法人日本薬学会の論文
- 1985-06-25
著者
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佐用 博照
Faculty of Pharmaceutical Sciences, Kobe-Gakuin University
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道田 隆
Faculty Of Pharmaceutical Sciences Osaka University
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道田 隆
Faculty Of Pharmaceutical Sciences Kobe-gakuin University
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佐用 博照
Faculty Of Pharmaceutical Sciences Kobe-gakuin University
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