Controlled Potential Electrolysis. X. Polarographic Behavior and Electrolytic Reduction Process of Esters of Aliphatic α-Nitrocarboxylic Acids
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概要
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Polarographic reduction mechanism of aliphatic ethyl nitrocarboxylates was investigated. The decrease of the wave height in alkaline region was ascribed to the conversion of the nitro form to aci-nitro anion rather than the ester hydrolysis. Only ethyl nitroacetate developed a wave for the aci-nitro anion. The coulometric n values and the products obtained, combined with the polarographic results, suggest the scheme (1) as the most probable reduction mechanism. The production of amine is only possible through C=N double bond formation, but not through hydroxyamino derivatives as usually suggested.
- 公益社団法人日本薬学会の論文
- 1964-12-25
著者
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枡井 雅一郎
Faculty Of Pharmaceutical Sciences Osaka University
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佐用 博照
Faculty of Pharmaceutical Sciences, Kobe-Gakuin University
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佐用 博照
Faculty Of Pharmaceutical Sciences Kobe-gakuin University
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岸 啓一
Faculty Of Pharmaceutical Sciences Osaka University
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