Anodic Oxidation of Amines. VIII. Oxidation of Ethane-1,2-diamines

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概要

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• Anodic oxidation of ethylenediamines (ethane-1,2-diamines) was investigated by cyclic voltammetry and controlled potential electrolysis in aqueous carbonate buffer (pH 10) at a glassycarbon electrode. The first wave of the diamines is developed at a lower potential than that of the corresponding β-alkanolamines. Among the oxidative bond cleavages, the relative amount of (α) C-(β) C bond fission is larger than that observed for β-alkanolamines and oxidative deamination is only observed after the (α) C-(β) C bond fission. A scheme for the reaction processes is proposed.

• 1984-03-25

著者

• 枡井 雅一郎

  Faculty Of Pharmaceutical Sciences Osaka University

• 鎌田 吉介

  Faculty Of Pharmaceutical Sciences Osaka University

• 尾崎 茂子

  Faculty of Pharmaceutical Sciences, Osaka University

• 尾崎 茂子

  Faculty Of Pharmaceutical Sciences Osaka University

• 枡井 雅一郎

  大阪大学薬学部

• 西田 英子

  Faculty of Pharmaceutical Sciences, Osaka University

• 西田 英子

  Faculty Of Pharmaceutical Sciences Osaka University

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