Anodic Oxidation of Amines. IX. Anodic Oxidation Process of α-Amino Acids in Aqueous Buffer of pH 10
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概要
- 論文の詳細を見る
Anodic oxidation of α-amino acids with and without a β-hydroxy group was investigated by cyclic voltammetry and controlled potential electrolysis in aqueous carbonate buffer of pH 10. The first wave of the α-amino acids is developed at nearly the same potentials as those observed for the corresponding simple aliphatic amines, showing that a β-hydroxy group does not significantly decrease the first oxidation potential, in contrast to the case of β-alkanolamines. Decarboxylation accompanied by dealkylation is the main reaction process, and a small amount of C-C bond fission also occurs only in the case of the β-hydroxy amino acids.
- 社団法人日本薬学会の論文
- 1984-12-25
著者
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桝井 雅一郎
Faculty of Pharmaceutical Sciences, Osaka University
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桝井 雅一郎
Faculty Of Pharmaceutical Sciences Osaka University
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鎌田 吉介
Faculty Of Pharmaceutical Sciences Osaka University
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尾崎 茂子
Faculty of Pharmaceutical Sciences, Osaka University
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飯塚 妙子
Faculty of Pharmaceutical Sciences, Osaka University
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尾崎 茂子
Faculty Of Pharmaceutical Sciences Osaka University
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桝井 雅一郎
Pharmaceutical Institute Medical Faculty University Of Tokyo
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飯塚 妙子
Faculty Of Pharmaceutical Sciences Osaka University
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