Chemical Transformation of Uronic Acids leading to Aminocyclitols. IV. Synthesis of Hexaacetyl-streptamine from N-Acetyl-D-glucosamine by Means of Electrolytic Decarboxylation
スポンサーリンク
概要
- 論文の詳細を見る
Through a short series of reactions (catalytic oxidation, electrolytic decarboxylation, cyclization with alkaline nitromethane, and reduction), a conversion of N-acetyl-D-glucosamine (1) into hexaacetyl-streptamine (6) has been accomplished without previous protection of the hydroxyl groups in the starting compound (1), although the overall yield was not fully satisfactory. The conversion may represent a new and widely applicable means for the synthesis of diaminocyclitols from amino-sugars. A β-methoxyethoxymethyl ether function was unaffected during the anodic oxidation.
- 公益社団法人日本薬学会の論文
- 1981-09-25
著者
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北川 勲
Faculty of Pharmaceutical Sciences, Osaka University
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吉川 雅之
Faculty of Pharmaceutical Sciences, Osaka University
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北川 勲
Faculty Of Pharmaceutical Sciences Osaka University
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上垣内 俊行
Faculty of Pharmaceutical Sciences, Osaka University
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池田 善治
Faculty of Pharmaceutical Sciences, Osaka University
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池田 善治
Faculty Of Pharmaceutical Sciences Osaka University
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上垣内 俊行
Faculty Of Pharmaceutical Sciences Osaka University
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