Studies on the Sulfur-containing Chelating Agents. XLIII. The Reaction of Thio-β-diketones and the Related Compounds with Iron (II) in the Presence of Pyridine
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概要
- 論文の詳細を見る
The formations of the adduct complex of the type (ligand)_2 Fe (II) (base) n (n=1 or 2) were observed in the reacton of some thio-β-diketones, and the corresponding β-diketones with iron (II) ion in the presence of pyridine base. Paramagnetic shifts were observed in γ-picoline adducts. The use of thiothenoyltrifluoroacetone, thiodibenzoylmethane and dibenzoylmethane gave satisfactory result in the determination of less than 60μg of iron as an extraction-spectrophotometric reagent, based on their adduct formation reaction with pyridine.
- 社団法人日本薬学会の論文
- 1975-03-25
著者
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田中 久
Faculty of Pharmaceutical Sciences, Kyoto University
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千熊 正彦
Faculty of Pharmaceutical Sciences, Kyoto University
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横山 陽
Faculty of Pharmaceutical Sciences, Kyoto University
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大井 泰子
Faculty of Pharmaceutical Sciences, Kyoto University
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横山 陽
Department Of Radiopharmaceutical Chemistry Faculty Of Pharmaceutical Sciences Kyoto University
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千熊 正彦
大阪薬科大学
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大井 泰子
Faculty Of Pharmaceutical Sciences Kyoto University
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