A Novel Method of Preparation of Bis (dithiobenzoylacetonato) Zn (II)
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概要
- 論文の詳細を見る
When methyliodide and water were added to sodium phenylpropiolthioanilide suspended in ether, C-methylation and C-N bond rupture occurred at the thioamido group. S-[1-Phenyl-2-(thioacetyl) vinyl] isothiuronium p-toluenesulfonate was obtained by adding thiourea and p-toluenesulfonic acid to the ether phase. This salt did not give a free ligand, dithiobenzoylacetone, but produced a zinc chelate, bis (dithiobenzoylacetonato)-Zn (II) by adding aqueous Zn^<2+> to the aqueous alkaline solution of the salt.
- 社団法人日本薬学会の論文
- 1978-07-25
著者
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田中 久
Faculty of Pharmaceutical Sciences, Kyoto University
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北川 進
Faculty of Pharmaceutical Sciences, Kyoto University
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北川 進
Faculty Of Pharmaceutical Sciences Kyoto University
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