Spectroscopic and Catalytic Properties of Penicillamine-Molybdenum Complexes
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概要
- 論文の詳細を見る
A new blue colored penicillamine-Mo complex was obtained at pH 9.2 under a reduction with sodium borohydride. This complex gives electron spin resonance signal which has high level of a monomeric Mo, and shows absorption maxima at 440 and 630 nm which could be assigned to d-d transitions arising from a ^4A_<2g> ground state. By an aeration, the Mo complex is oxidized to the yellow colored dioxo-bridged Mo^V complex. The catalytic activity of the penicillamine-Mo complexes has been investigated by the reduction of acetylene to ethylene and ethane in the presence of borohydride.
- 社団法人日本薬学会の論文
- 1977-02-25
著者
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田中 久
Faculty of Pharmaceutical Sciences, Kyoto University
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杉浦 幸雄
Faculty of Pharmaceutical Sciences, Kyoto University
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杉浦 幸雄
京大薬
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杉浦 幸雄
Faculty Of Pharmaceutical Sciences Kyoto University
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菊池 孝信
Faculty of Pharmaceutical Sciences, Kyoto University
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菊池 孝信
Faculty Of Pharmaceutical Sciences Kyoto University
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