Studies on Sulfur-containing Chelating Agents. IX. Syntheses of Alkyl or Aryl o-Mercaptophenyl Ketones, Esters of o-Mercaptobenzoic Acid, S-Esters of o-Mercaptothiobenzoic Acid, and their Metal Chelates.
スポンサーリンク
概要
- 論文の詳細を見る
Alkyl or aryl o-mercaptophenyl ketones, esters of o-mercaptobenzoic acid and S-esters of o-mercaptothiobenzoic acid were synthesized, expecting their strong chelating ability due to the presence of aromatic mercapto group and double bond of benzene ring. Alkyl or aryl o-mercaptophenyl ketones were unstable and could not be investigated in detail. Esters of o-mercaptobenzoic acid and S-esters of o-mercaptothiobenzoic acid formed a chelate with cobalt, nickel, and copper in a ratio of 3 : 1,2 : 1,and 1 : 1,respectively. These ligands were sensitive to nickel and palladium.
- 公益社団法人日本薬学会の論文
- 1962-01-25
著者
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田中 久
Faculty of Pharmaceutical Sciences, Kyoto University
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横山 陽
Faculty of Pharmaceutical Sciences, Kyoto University
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横山 陽
Department Of Radiopharmaceutical Chemistry Faculty Of Pharmaceutical Sciences Kyoto University
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