3-Ketoglucuronic Acid. II. Constitution and Chemical Properties of 3-Ketoglucuronic Acid
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概要
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Periodate oxidation of 3-ketoglucuronic acid indicated the presence of hemiacetal ring structure and in consequence the uronic acid was assigned as 3-keto-D-glucopy-ranuronic acid (III), which on treatment with cation resin in methanol gave methyl furanoside (V). Enolization of 3-ketoglucuronic acid between C-2 and C-3 was confirmed by conversion of the Keto-acid into the corresponding enol ether, namely methyl 3-O-methyl-D-glucopyranoenediol-(2,3)-uronate (VIII). Equilibrium between keto-and enol from of this keto-sugar in an aqueous solution was, however, found to be inclined predominantly to the keto-form (III) by means of polarography.
- 公益社団法人日本薬学会の論文
- 1966-09-25
著者
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田村 善蔵
Faculty of Pharmaceutical Sciences, University of Tokyo
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木下 俊夫
School of Pharmaceutical Sciences, Kitasato University
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石館 守三
Tokyo Biochemical Research Institute
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田村 善蔵
Faculty Of Pharmaceutical Sciences University Of Tokyo
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田村 善蔵
Pharmaceutical Institute School Of Medicine Keio University
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木下 俊夫
School Of Pharmaceutical Sciences Kitasato University
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木下 俊夫
Faculty of Pharmaceutical Sciences, University of Tokyo
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